https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:41276 2 have been successfully stabilized and uniformly distributed on the surface of n-butyl triethyl ammonium bromide functionalized polypyrrole/graphene oxide (BTAB/PPy/GO) by a very simple hydrothermal method. BTAB as a typical kind of quaternary ammonium-type ionic liquids (ILs) played a crucial role in the formation of the obtained 1T-MoS₂/BTAB/PPy/GO. It was covalently linked with PPy/GO and arranged in a highly ordered order at the solid–liquid interface of PPy/GO and H₂O due to Coulombic interactions and other intermolecular interactions, which would induce and stabilize ultrathin 1T-MoS₂ nanoplates by morphosynthesis. The good electrocatalytic activity toward nitrogen reduction reaction (NRR) with strong durability and good stability can be achieved by 1T-MoS₂/BTAB/PPy/GO due to their excellent inorganic/organic hierarchical lamellar micro-/nanostructures. Especially, after the long-term electrocatalysis for NRR at a negative potential, metastable 1T-MoS2 as the catalytic center undergoes two types of irreversible crystal phase transition, which was converted to 1T′-MoS₂ and Mo₂N, caused by the competitive hydrogen evolution reaction (HER) process and the electrochemical reaction between the electroactive 1T-MoS₂ and N₂, respectively. The new N–Mo bonding prevents Mo atoms from binding to other N atoms in N₂, resulting in the deactivation of the electrocatalysts to NRR after being used for 18 h. Even so, quaternary ammonium-type ILs would induce the crystal structures of transition-metal dichalcogenides (TMDCs), which might provide a new thought for the reasonable design of electrocatalysts based on TMDCs for electrocatalysis.]]> Mon 01 Aug 2022 10:10:30 AEST ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:38932 -2, a small Tafel slope of 87 mV dec^-1 and prominent durability. Percolation theory was for the first time introduced to interpret the catalytic mechanism of the CD/CF catalysts. The special morphology assembled by the 0D carbons constituted the percolating clusters and promoted electron transport throughout the 1D carbons. The strategy and theory can be adapted to general electrocatalytic applications for achieving and interpreting precise tuning on highly efficient electron transfer in electrocatalysts.]]> Fri 15 Sep 2023 15:54:21 AEST ]]> https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:47309 Fri 13 Jan 2023 10:59:50 AEDT ]]>